A New Preparative Method for Allylic Indium(III) Reagents by Reductive Transmetalation of pi-Allylpalladium(II) with Indium(I) Salts |
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| Authors: | Araki Kamei Hirashita Yamamura Kawai |
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| Institution: | Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan. |
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| Abstract: | A reductive transmetalation of the pi-allylpalladium(II) complexes, generated in situ from a catalytic amount of a palladium(0) complex and a variety of allylic substrates, with indium(I) salts proceeded smoothly in various solvents, providing a new route for allylindium(III) reagents. |
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