Palladium-mediated ring opening of hydroxycyclopropanes |
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| Authors: | Park Cha |
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| Institution: | Department of Chemistry, University of Alabama, Tuscaloosa 35487, USA. |
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| Abstract: | reaction: see text] The palladium-mediated ring opening of substituted cyclopropanols has been found to take place predominantly at the less substituted C-C bond. Thus, sequential application of the titanium-mediated cyclopropanation of esters and the palladium-mediated ring opening of the resulting cyclopropanols provides a convenient method for functionalizing monosubstituted olefins. |
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