| 二氧化碳-氧化环己烯的共聚反应 |
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| 引用本文： | 张南燕,陈立班,杨淑英,余爱芳,何树杰.二氧化碳-氧化环己烯的共聚反应[J].广州化学,2000,25(2):1-6. |
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| 作者姓名： | 张南燕 陈立班 杨淑英 余爱芳 何树杰 |
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| 作者单位： | 中国科学院广州化学研究所,广州,510650 |
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| 基金项目： | 中国科学院资助项目，29734120， |
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| 摘 要： | 由CO2 -氧化环己烯 (CHO)配位催化共聚制得高Tg 的脂肪族聚环己基撑碳酸酯 ,并用IR、NMR和DSC等进行了表征 ,用TG对聚合物的热稳定性进行了分析。加入异氰酸苯酯有提高产物特性粘数的作用。
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| 关 键 词： | 二氧化碳 氧化环己烯 环氧丙烷 共聚反应 玻璃化转变温度 热稳定性 |
| 修稿时间： | 1999－08－30 |
Copolymerization of Carbon Dioxide and Cyclohexene Oxide by Polymer-Supported Bimetallic Catalysts |
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| Zhang Nanyan,Chen Liban,Yang Shuying,Yu Aifang,He Shujie.Copolymerization of Carbon Dioxide and Cyclohexene Oxide by Polymer-Supported Bimetallic Catalysts[J].Guangzhou Chemistry,2000,25(2):1-6. |
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| Authors: | Zhang Nanyan Chen Liban Yang Shuying Yu Aifang He Shujie |
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| Abstract: | Aliphatic poly(cyclohexene carbonate),which has a T g of 120℃,was synthesized by coordinate-catalytical copolymerization of carbon dioxide and cyclohexene oxide (CHO) with polymer-supported bimetallic catalyst (PBM) and was characterized by IR,NMR and DSC measurements.The thermal degradation of copolymers was studied by TG measurement, and found that 5% and 50% weight loss temperature (t 5% ,t 50% ) were 177℃ and 273℃, respectively. “End capping” can raise t 5% to 210℃.The copolymerization of CO 2, cyclohexene oxide (CHO) and phenyl isocyanate (PI) can increase the intrinsic viscosity (η]) but decrease the T g. |
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| Keywords: | carbon dioxide cyclohexene oxide propylene oxide copolymerization glass transition temperature thermostability |
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