The Isolation of a Large Cyclopentadienylcobaltsulfide Cluster. The Synthesis and Crystal Structure of Octahedral closo-(η5-C5H5Co)5S |
| |
| Authors: | Ryan L Holland Joseph M O’Connor Arnold L Rheingold |
| |
| Institution: | (1) Department of Chemistry and Biochemistry, University of California, La Jolla, San Diego, CA 92093-0358, USA |
| |
| Abstract: | The title cluster, which was obtained serendipitously when (η5-C5H5)Co(PPh3)2 was added to a (η5-C5H5)Co metallacyclobutene containing a sulfone group, is the largest cluster known, formed primarily with (η5-C5H5)Co vertices. The closo-(η5-C5H5Co)5S is a closed-shell, octahedral cluster which forms black, monoclinic crystals from methanol. |
| |
| Keywords: | Cyclopentadienylcobalt-sulfide cluster Isolobal analogue Closo-octahedral complex |
| 本文献已被 SpringerLink 等数据库收录！ |
|
