Total synthesis of (-)-goniotrionin |
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| Authors: | Dias Luiz C Ferreira Marco A B |
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| Institution: | Chemistry Institute, State University of Campinas, UNICAMP, 13083-970, C.P. 6154, Campinas, SP, Brazil. ldias@iqm.unicamp.br |
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| Abstract: | A stereoselective total synthesis of the reported structure of goniotrionin (4) has been accomplished. The key steps involved the opening of a chiral epoxide, a highly diastereoselective Mukaiyama aerobic oxidative cyclization, a selective 1,2-syn Mukaiyama aldol reaction, and a Noyori reduction. |
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