Molecular engineering and solvent dependence of excitation energy hopping in self-assembled porphyrin boxes |
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Authors: | Bahng Hee Won Kim Pyosang Sung Young Mo Maeda Chihiro Osuka Atsuhiro Kim Dongho |
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Affiliation: | Department of Chemistry, Yonsei University, Seoul 120-749, Korea. |
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Abstract: | It has been demonstrated that the direction and magnitude of transition dipole moments, and hence rates in the excitation energy hopping in the self-assembled porphyrin boxes can be tuned by insertion of ethynyl groups as well as the dielectric constant of solvent. |
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