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Molecular engineering and solvent dependence of excitation energy hopping in self-assembled porphyrin boxes
Authors:Bahng Hee Won  Kim Pyosang  Sung Young Mo  Maeda Chihiro  Osuka Atsuhiro  Kim Dongho
Affiliation:Department of Chemistry, Yonsei University, Seoul 120-749, Korea.
Abstract:It has been demonstrated that the direction and magnitude of transition dipole moments, and hence rates in the excitation energy hopping in the self-assembled porphyrin boxes can be tuned by insertion of ethynyl groups as well as the dielectric constant of solvent.
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