Unimolecular ligand-initiator dual functional systems (ULIS) for low copper ATRP of vinyl monomers including acrylic/methacrylic acids |
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| Authors: | Jana Satyasankar Parthiban Anbanandam Choo Foo Ming |
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| Institution: | Institute of Chemical and Engineering Sciences, Agency for Science, Technology and Research, 1, Pesek Road, Jurong Island, Singapore, 627833. |
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| Abstract: | A novel approach for ATRP has been developed which enables the polymerization of vinyl monomers including those bearing carboxylic acid groups such as acrylic/methacrylic acid in the free acid form with ppm amounts of copper. The quantity of copper used in the polymerization is comparable to those left in purified polymers obtained by a conventional ATRP process. |
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