Hangman effect on hydrogen peroxide dismutation by Fe(III) corroles |
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| Authors: | Graham Daniel J Dogutan Dilek K Schwalbe Matthias Nocera Daniel G |
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| Affiliation: | Department of Chemistry, 6-335, Massachusetts Institute of Technology, Cambridge, MA 02139, USA. |
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| Abstract: | Hangman Fe(III) corroles catalyse H(2)O(2) disproportionation at a faster rate and display a more pronounced hangman effect than their one electron oxidized analogues owing to their ability to bypass high energy intermediates by redox-leveling derived from the use of the corrole as a non-innocent ligand. |
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