| 几个TTF衍生物的电荷转移情况研究 |
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| 引用本文： | 刘永成,姚钟麒.几个TTF衍生物的电荷转移情况研究[J].宁波大学学报(理工版),1991(2). |
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| 作者姓名： | 刘永成 姚钟麒 |
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| 作者单位： | 宁波大学应用与工程化学研究室，中国科学院兰州化学物理研究所 |
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| 摘 要： | 本文报道了用循环伏安法研究了几个 TTF 衍生物的电荷转移情况,发现都是两个单电子转移的可逆氧化还原波,其半波电位受溶剂的极性和电子效应影响较大,在 CH_2Cl_2溶液中,其 E_(1/2)大小顺序为:TMT-TTF
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| 关 键 词： | TTF 循环伏安 UV 分子内电荷转移 表面光电压 |
STUDY ON CHARGE TRANSFER OF SOME TTF DERIVANTS |
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| Liu Yongcheng.STUDY ON CHARGE TRANSFER OF SOME TTF DERIVANTS[J].Journal of Ningbo University(Natural Science and Engineering Edition),1991(2). |
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| Authors: | Liu Yongcheng |
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| Abstract: | The charge transfer of some TTF derivants was studied.These TTF derivants undergo two successive reversible one-electron transfer reactions in nonaqueous solutions.The half wave potentials of them are influenced by the polarities and electronic effects of solvents.In CH_2Cl_2 solution,the order of E_(1/2)is TMT-TTF
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| Keywords: | TTF cyclic voltammetry UV intramolecular charge-transfer surface photovoltage |
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