Photogeneration of heptacene in a polymer matrix |
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| Authors: | Mondal Rajib Shah Bipin K Neckers Douglas C |
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| Institution: | Center for Photochemical Sciences, Bowling Green State University, Bowling Green, Ohio 43403, USA. |
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| Abstract: | Heptacene (1) was generated by the photodecarbonylation of 7,16-dihydro-7,16-ethanoheptacene-19,20-dione (2) in a polymer matrix using a UV-LED lamp (395 +/- 25 nm). Compound 1 showed a long wavelength absorption band extending from 600 to 825 nm (lambdamax approximately 760 nm) and was found to be stable up to 4 h in the polymer matrix. However, irradiation of a solution of 2 in toluene produced only oxygen adducts. |
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