Emission of Ag2 dimers from a substrate during vacuum deposition of the mixture of silver and water vapor

The work presents calculation of Ag₂ dimers emission from the substrate into the vapor medium in case of joint deposition of silver and water vapors on ideal substrate formally modeling the crystal of water ice in terms of energy properties. It is assumed that the dimers are formed on the condensation surface as a result of random collisions of atoms at their surface migration, and the dimers emission is conditioned by thermal fluctuations of crystal lattice of water ice. The calculations based on the modified Langmuir adsorption model allowed concluding that emission of silver and water dimers takes place in the entire range of the studied water vapor pressure, binding energy of silver-water, and crystal temperature. Dynamics of emission from the beginning of deposition and dependence of dimers emission on micro-roughness of the condensate surface have been investigated. Statistical processing of results has shown that the probability of dimers emission from the condensate surface is determined not only by the value of the binding energy between the dimer and condensate but by configuration of the nearest dimer environment on the condensation surface. It has been found that there is a certain value of micro-roughness of condensation surface providing the maximal intensity of dimer emission. Dimers emission from the surfaces bordering on the flows of vapor mixtures contaminates the flows with unsuspected admixtures. The latter one makes investigation of this phenomenon important for aeromechanics of vapor and gas mixtures.