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含硅多金属氧酸盐的抑菌作用
引用本文:陈丙年,冯珍鸽,王力. 含硅多金属氧酸盐的抑菌作用[J]. 高等学校化学学报, 2011, 32(5): 1033-1036
作者姓名:陈丙年  冯珍鸽  王力
作者单位:1. 集美大学生物工程学院, 厦门 361021; 2. 厦门大学附属中山医院演武分院(厦门大学医院), 厦门 361005
摘    要:本文按文献方法合成了α-1,2,3-K6H[SiW9V3O40]、α-1,2-K6[SiW10V2O40]和α-K5[SiW11VO40](以下分别简写为α-SiW9V3,α-SiW10V2,α-SiW11V)3种多金属氧酸盐,并通过紫外和红外光谱对3种多金属氧酸盐化合物结构进行了表征。利用纸片法研究了3种钒取代的硅钨酸盐及硅钨酸(H4SiW12O40?xH2O,简写为SiW12)对大肠杆菌、枯草芽孢杆菌、酵母菌、黑曲霉和青霉的抑菌活性。结果表明:4种物质对大肠杆菌、枯草芽孢杆菌、酵母菌和黑曲霉均有不同程度的抑菌效果,但对青霉的抑菌效果较差。由于引起果蔬腐败的微生物主要有细菌、杆菌、霉菌和酵母菌等,本实验将为多金属氧酸盐作为广谱高效果蔬保鲜剂提供理论依据。

关 键 词:多金属氧酸盐   抑菌活性   纸片法  
收稿时间:2010-09-07

Antibacterial Activities of Polyoxometalates Containing Silicon
CHEN Bing-Nian,FENG Zhen-Ge,WANG Li. Antibacterial Activities of Polyoxometalates Containing Silicon[J]. Chemical Research In Chinese Universities, 2011, 32(5): 1033-1036
Authors:CHEN Bing-Nian  FENG Zhen-Ge  WANG Li
Affiliation:1. School of Biotechnology, Jimei University, Xiamen 361021, China;2. Yanwu Affiliated Hospital of Zhongshan Hospital of  Xiamen University(Xiamen University Hospital), Xiamen 361005, China
Abstract:The polyoxometalates α-1,2,3-K6H[SiW9V3O40], α-1,2-K6[SiW10V2O40] and α-K5[SiW11VO40] (abbreviated as α- SiW9V3, α-SiW10V2, α-SiW11V, respectively) were synthesized and characterized by UV-Vis and FT–IR spectrums. The antibacterial activity of four polyoxometalates against common bacteria(Escherichia coli, Bacillus subtilis, yeast, Aspergillus niger and Penicillium) was studied by disk diffusion method. The results indicated that four compounds showed different antibacterial effects on Escherichia coli, Bacillus subtilis, yeast, Aspergillus niger, and the antibacterial activity of Penicillium was relatively worse. This study should give theoretical support for polyoxometalate used as a fruit and vegetable preservative agent.
Keywords:Polyoxometalates  Antibacterial activity  Disk diffusion method
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