Coordination compounds of some d metals with anthrapyridinedione derivatives: Crystal structure of 2-phenyl-4-(piperidyl-1)-anthra[1,2-b]pyridine-7,12-dionium hexabromodicuprate(II) (HL1)2[Cu2Br6] |
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Authors: | S B Strashnova A B Ilyukhin O V Koval’chukova P V Strashnov V S Sergienko B E Zaitsev |
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Institution: | 1. People??s Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow, 117198, Russia 2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
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Abstract: | Complexes of copper(II), nickel(II), and cobalt(II) chlorides and bromides with 2-phenyl-4-(piperidyl-1)-anthra1,2-b]pyridine-7,12-dione (L1) and 2-phenyl-4-(octylamino)-anthra1,2-b]pyridine-7,12-dione (L2) were synthesized from neutral and acidic media. The molecular and crystal structure of 2-phenyl-4-(piperidyl-1)-anthra1,2-b]pyridine-7,12-dionium hexabromodicuprate(II) (HL1)2Cu2Br6] was determined by X-ray diffraction analysis. The spectral characteristics of L1 and L2 and their complexes are presented. Formation of their complexes in solutions was studied. |
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