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Resonance Raman studies of photochemical molecular devices for multielectron storage |
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| Authors: | Stefanie Tschierlei,Benjamin Dietzek,Michael Karnahl,Sven Rau,Frederick M. MacDonnell,Michael Schmitt,Jü rgen Popp |
| Abstract: | Resonance Raman spectroscopy was utilized for the first time to characterize the nature of the 1metal‐to‐ligand charge transfer (MLCT) state of a ruthenium complex containing the redoxactive tetraazatetrapyrido‐pentacene (tatpp) ligand. The presented results show that the long‐wavelength absorption is originating from transitions involving the terminal phenanthroline and the tatpp ligands. Copyright © 2008 John Wiley & Sons, Ltd. |
| Keywords: | charge transfer resonance Raman spectroscopy ruthenium complexes |