Synthesis of cyclitols via ring-closing metathesis |
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| Institution: | 1. Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes, “Organométalliques: Matériaux et Catalyse”, Campus de Beaulieu, 35042 Rennes, France;2. Laboratoire de Chimie Appliquée et Environnement (LCAE-URAC18), Faculté des Sciences, Université Mohamed Premier, Oujda, Morocco;3. Faculté Pluridisciplinaire de Nador, Université Mohammed Premier, BP: 300, Selouane 62700, Nador, Morocco;1. University of Insubria, Department of Science and High Technology and CIRCC, Via Valleggio 9, 22100 Como, Italy;2. Institute of Chemistry, University of Neuchâtel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland;1. Civil Engineering Department, University College Dublin, Ireland;2. Department of Maritime Technologies, BAUER Maschinen GmbH, Schrobenhausen, Germany |
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| Abstract: | A convenient synthesis of enantiomerically pure and differentially protected l-chiro- and myo-inositols as well as conduritols B and F from 2,3,4-tri-O-benzyl-d-xylopyranose via ring-closing metathesis is reported. The facile synthesis of conduritol B constitutes a short formal synthesis of (?)-cyclophellitol. |
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