Highly phosphorescent crystals of vaulted trans-bis(salicylaldiminato)platinum(II) complexes |
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| Authors: | Komiya Naruyoshi Okada Minoru Fukumoto Kanako Jomori Daisuke Naota Takeshi |
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| Affiliation: | Department of Chemistry, Graduate School of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-8531, Japan. |
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| Abstract: | Unprecedented strong phosphorescent emission in the crystalline state is observed for a variety of vaulted trans-bis(salicylaldiminato)platinum(II) complexes which are newly synthesized as a third coordination mode of well-studied bis(salicylaldiminato) complexes. This Communication describes the dynamic photophysical properties of these complexes in the liquid and crystalline states and a mechanistic rationale for the strong emission in the crystalline state. |
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