A tetranuclear, macrocyclic 3d-4f complex showing single-molecule magnet behavior |
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| Authors: | Feltham Humphrey L C Clérac Rodolphe Powell Annie K Brooker Sally |
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| Affiliation: | Department of Chemistry and MacDiarmid Institute, University of Otago, P.O. Box 56, Dunedin 9054, New Zealand. |
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| Abstract: | [Cu(II)(3)Tb(III)(L(Pr))(NO(3))(2)(MeOH)(H(2)O)(2)](NO(3))·3H(2)O is a rare example of a 3d-4f single-molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency-dependent alternating-current susceptibility, indicative of slow relaxation of the magnetization. |
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