Catalytic asymmetric aza-Darzens reaction with a vaulted biphenanthrol magnesium phosphate salt |
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Authors: | Larson Shawn E Li Guilong Rowland Gerald B Junge Denise Huang Rongcai Woodcock H Lee Antilla Jon C |
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Institution: | Department of Chemistry, University of South Florida, 4202 East Fowler Avenue CHE205A, Tampa, Florida 33620, United States. |
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Abstract: | Conditions for a catalytic asymmetric aza-Darzens aziridine synthesis mediated by a vaulted biphenanthrol (VAPOL) magnesium phosphate salt is described. Using simple substrates, this methodology explores the scope and reactivity of a new magnesium catalyst for an aziridination reaction capable of building chirality and complexity simultaneously. |
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