Nonhydride mechanism of metal-catalyzed hydrosilylation |
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| Authors: | Shirobokov Oleg G Kuzmina Lyudmila G Nikonov Georgii I |
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| Institution: | Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, Ontario L2S 3A1, Canada. |
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| Abstract: | A 1:1:1 reaction between complex (Tp)(ArN═)Mo(H)(PMe(3)) (3), silane PhSiD(3), and carbonyl substrate established that hydrosilylation catalyzed by 3 is not accompanied by deuterium incorporation into the hydride position of the catalyst, thus ruling out the conventional hydride mechanism based on carbonyl insertion into the M-H bond. An analogous result was observed for the catalysis by (O═)(PhMe(2)SiO)Re(PPh(3))(2)(I)(H) and (Ph(3)PCuH)(6). |
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