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Rh(I)/Sc(OTf)3-co-catalyzed Michael addition of ammonium ylide to (E)-1,4-enediones: synthesis of functionalized 1,4-diketones |
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| Authors: | Wei Qinghua Li Zi Yang Xi Chen Jianghui Liu Xiaohua Hu Wenhao Liu Shunying |
| Institution: | 1.Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200062, China ;2.School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou, 510006, China ;3.Key Laboratory of Green Chemistry and Technology Ministry of Education, College of Chemistry, Sichuan University, Chengdu, 610064, China ; |
| Abstract: | Molecular Diversity - A Rh(I)/Sc(III) co-catalyzed synthesis of highly valuable functionalized 1,4-diketone derivatives in good yields and with an excellent diastereoselectivity. The established... |
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