| 正烷基单胺对层状甘氨酸-N，N-双甲基膦酸锆的插层 |
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| 引用本文： | 杨新斌,傅相锴,曾仁权,隋岩.正烷基单胺对层状甘氨酸-N，N-双甲基膦酸锆的插层[J].无机化学学报,2006,22(2):326-330. |
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| 作者姓名： | 杨新斌 傅相锴 曾仁权 隋岩 |
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| 作者单位： | 1. 西南大学荣昌校区基础部,重庆,402460
2. 西南大学化学化工学院应用化学研究所,重庆,400715 |
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| 摘 要： | The layered zirconium glycine-N,N-dimethylphosphonate (ZGDMP) was prepared and the intercalation behavior of n-alkylmonoamines was investigated. The X-ray diffraction powder patterns demonstrated that the n-alkylmonoamines were taken up in one step and there were no other intermediate phases. The interlayer distance correlated with the number of carbon atoms of the n-alkylmonoamine chains. The n-alkylmonoamines were intercalated into ZGDMP in such a way that the protons of the interlayer -CO2H groups were replaced by the terminal -NH3+ of the protonated n-alkylmonoamines. The intercalated n-alkylmonoamines were released from the lamellar ZGDMP at temperature of 150 to 250 ℃.
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| 关 键 词： | 甘氨酸-N，N-双甲基膦酸锆 插层 正烷基单胺 |
| 文章编号： | 1001-4861(2006)02-0326-05 |
| 收稿时间： | 2005-07-08 |
| 修稿时间： | 2005-10-07 |
Intercalation of n-Alkylmonoamine into Layered Zirconium Glycine-N, N-Dimethylphosphonate |
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| YANG Xin-Bin,FU Xiang-Kai,ZENG Ren-Quan and SUI Yan.Intercalation of n-Alkylmonoamine into Layered Zirconium Glycine-N, N-Dimethylphosphonate[J].Chinese Journal of Inorganic Chemistry,2006,22(2):326-330. |
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| Authors: | YANG Xin-Bin FU Xiang-Kai ZENG Ren-Quan and SUI Yan |
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| Institution: | Department of Basic Science, Rongchang Campus, Southwest University, Chongqing 402460,School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715,Department of Basic Science, Rongchang Campus, Southwest University, Chongqing 402460 and School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715 |
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| Abstract: | The layered zirconium glycine-N,N-dimethylphosphonate (ZGDMP) was prepared and the intercalation behavior of n-alkylmonoamines was investigated. The X-ray diffraction powder patterns demonstrated that the n-alkylmonoamines were taken up in one step and there were no other intermediate phases. The interlayer distance correlated with the number of carbon atoms of the n-alkylmonoamine chains. The n-alkylmonoamines were intercalated into ZGDMP in such a way that the protons of the interlayer-CO2H groups were replaced by the terminal -NH3+ of the protonated n-alkylmonoamines. The intercalated n-alkylmonoamines were released from the lamellar ZGDMP at temperature of 150 to 250 ℃. |
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| Keywords: | zirconium glycine-N N-dimethylphosphonate intercalation n-alkylmonoamine |
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