Matrix-isolation Raman spectroscopy and photochemistry of carbonyl-metal-silyl complexes |
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| Authors: | C Fickert R Pikl D Gernet S Möller W Malisch W Kiefer |
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| Institution: | 1. Institut für Physikalische Chemie der Universit?t Würzburg, Marcusstrasse 9–11, D-97070, Würzburg, Germany
2. Institut für Anorganische Chemie der Universit?t Würzburg, Am Hubland, D-97074, Würzburg, Germany
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| Abstract: | To study the photochemistry of metal-silyl complexes the compounds Cp(CO)(2)Fe-SiH(2)(CH(3)) (Cp = eta(5)-C(5)H(5)) and Cp*(CO)(2)((CH(3))(3)P)Mo-SiH(3) (Cp* = eta(5)-C(5)(CH(3))(5)) have been isolated in krypton or nitrogen matrices and subsequently detected by Raman spectroscopy. Vibrational assignments for the two compounds are given. Furthermore, differences in the Raman spectra induced by UV irradiation are discussed. |
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