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Synthesis and properties of 1,1′-bis(diacetylene-group) connected ferrocene-thiophene derivative: a cooperatively functional behavior of diacetylene-group connected constituents
Authors:Junro YoshinoEmi Hasegawa  Naoto HayashiHiroyuki Higuchi
Institution:Graduate School of Science and Engineering, University of Toyama, 3190 Gofuku, Toyama, Toyama 930-8555, Japan
Abstract:An extended π-electronic conjugation system of 1,1′-bis(diacetylene-group) connected ferrocene-thiophene derivative has been synthesized, with our integrated reaction between the corresponding TMS-protected acetylenes in one-pot. Its electronic properties have been examined, suggesting a cooperatively functional behavior of the diacetylene-group connected constituents.
Keywords:Diacetylene  Ferrocene  Thiophene  Integrated reaction  Electronic property  Material science
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