Thermochromism of CuI Tetrakisguanidine Complexes: Reversible Activation of Metal‐to‐Ligand Charge‐Transfer Bands |
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Authors: | Sven Wiesner Arne Wagner Dr Olaf Hübner Dr Elisabeth Kaifer Prof Hans‐Jörg Himmel |
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Institution: | Anorganisch‐Chemisches Institut, Ruprecht‐Karls Universit?t Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg (Germany), Fax: (+49)?6221‐545707 |
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Abstract: | Tetranuclear, intensely blue‐coloured CuI complexes were synthesised in which two Cu2X3? units (X=Br or I) are bridged by a dicationic GFA (guanidino‐functionalised aromatic) ligand. The UV/Vis spectra show a large metal‐to‐ligand charge‐transfer (MLCT) band around 638 nm. The tetranuclear “low‐temperature” complexes are in a temperature‐dependent equilibrium with dinuclear CuI “high‐temperature” complexes, which result from the reversible elimination of two CuX groups. A massive thermochromism effect results from the extinction of the strong MLCT band upon CuX elimination with increasing temperature. For all complexes, quantum chemical calculations predict a small and method‐dependent energy difference between the possible electronic structures, namely CuI and dicationic GFA ligand (closed‐shell singlet) versus CuII and neutral GFA ligand (triplet or broken‐symmetry state). The closed‐shell singlet state is disfavoured by hybrid‐DFT functionals, which mix in exact Hartree–Fock exchange, and is favoured by larger basis sets and consideration of a polar medium. |
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Keywords: | charge‐transfer coordination compounds copper electronic structure guanidine redox‐active ligands |
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