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A practical synthesis of aryl sulfones via cross-coupling of sulfonyl hydrazides with aryltriazenes using copper/ionic liquid combination
Authors:Anand Kumar Pandey  Saurabh Kumar  Rahul Singh  Krishna Nand Singh
Institution:Department of Chemistry (Centre of Advanced Study), Institute of Science, Banaras Hindu University, Varanasi, 221005, India
Abstract:A new and efficient approach adopting copper-catalyzed cross-coupling of sulfonyl hydrazides with aryltriazenes has been developed to synthesize aryl sulfones using Brønsted acidic ionic liquid as promoter under ambient conditions. The process employs stable and easy to handle reacting partners, and is endowed with broad substrate scope.
Keywords:Aryl sulfones  Sulfonyl hydrazides  Aryltriazenes  Cross-coupling  Copper-catalysis  Ionic liquids
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