Porphyrin-carborane organometallic assemblies based on 1, 2-dicarba-closo-dodecaborane (12) ligands |
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| Authors: | Wang Jian-Qiang Ren Chun-Xia Weng Lin-Hong Jin Guo-Xin |
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| Institution: | Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China. |
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| Abstract: | The assembly of soluble, air-stable, supramolecular structures {(Zn-TPyP)Cp*Ir{S2C2(B10H10)}]4(THF)2}(2), {(Cu-TPyP)Cp*Ir{S2C2(B10H10)}]4(THF)2}(3) and {(Zn-TPyP)Cp*Ir{S2C2(B10H10)}]2.6(CHCl3)}n (4), based on metal-containing moieties Cp*Ir{S2C2(B10H10)}] (1) bridged by nitrogen-based organic spacers, are described. |
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