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Synthesis and Structural Characterization of a Ruthenium Complex:trans-RuCl_2(COD)Py_2 |
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| Authors: | WANG Fanga b LIU Jun-Huaa b YIN Yuan-Qia XU Xian-Luna a |
| Affiliation: | WANG Fang~a,b LIU Jun-Hua~a,b YIN Yuan-Qi~a XU Xian-Lun~a a |
| Abstract: | A new ruthenium complex trans-RuCl2(COD)Py2 has been synthesized and charac- terized by elemental analysis, IR, 1H NMR and single-crystal X-ray diffraction. Crystal data: trans- RuCl2(COD)Py2, Mr = 438.35, monoclinic, space group P21/c, a = 8.9116(9), b = 14.6175(15), c = 13.7582(14) , β = 101.994(1)°, V = 1753.1(3) 3, Z = 4, Dc = 1.661 g/cm3 , F(000) = 888, μ = 1.199 mm-1, R = 0.0376 and wR = 0.0789 for 2492 observed reflections with I > 2σ(I). |
| Keywords: | ruthenium complex X-ray diffraction crystal |
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