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Oxazoles formation during O‐alkylation of isonitroso‐naphthols. X‐ray structure of [1,2]naphthoquinone 1‐[O‐(4‐tert‐butyl‐benzyl)‐oxime] and 2‐(4‐tert‐butyl‐phenyl)napth[1,2‐d]oxazole
Authors:Paola Astolfi  Patricia Carloni  Riccardo Castagna  Lucedio Greci  Pierluigi Stipa  Corrado Rizzoli
Abstract:1‐Nitroso‐2‐naphthol and 2‐nitroso‐1‐naphthol, both in the isonitroso form, react with benzyl bromides in THF and in the presence of triethylamine affording, in low yields, the corresponding O‐benzyl oximes and 2‐aryl naphthoxazoles in a 1:1 ratio, approximately. The structures of O‐benzyl oximes and naphthoxazoles isolated have been determined by X‐ray analysis.
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