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Application of ionic liquid doped solid polymer electrolyte
Authors:Pramod K Singh  Nitin A Jadhav  S K Mishra  U P Singh and B Bhattacharya
Institution:(1) Material Research Laboratory, Department of Physics, School of Engineering and Technology, Sharda University, Greater Noida, 201 306, India;(2) Research and Technology Development Centre, Sharda University, Greater Noida, 201 306, India;(3) School of Electronics Engineering, KIIT University, Bhubaneswar, 751024, Orissa, India
Abstract:The electrical, structural, and photoelectrochemical properties of the polymer electrolyte PEO:NaI/I2 doped with an ionic liquid 1-ethyl 3-methylimidazolium dicyanamide (EMImDCN) have been reported. Incorporation of the ionic liquid (IL) increases the membrane homogeneity, decreased surface roughness, and enhances the short current (J sc). Additionally, the doping of IL provides more charge carriers which enhances overall ionic conductivity (σ). The optimized σ was found at 40 wt.% IL composition. The fabricated DSSC using this new solid electrolyte showed 1.43% efficiency at 100 mW cm−2.
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