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Diastereo- and enantioselective intramolecular C(sp3)-H arylation for the synthesis of fused cyclopentanes |
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| Authors: | Martin Nicolas Pierre Cathleen Davi Michaël Jazzar Rodolphe Baudoin Olivier |
| Institution: | Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne, France. |
| Abstract: | All C-H bonds are not equal: The intramolecular arylation of unactivated C(sp(3))-H bonds in the presence of a chiral Pd/binepine catalyst allows the synthesis of fused cyclopentanes efficiently and in an diastereo- and enantioselective manner (see scheme). |
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