Temperature-triggered gate opening for gas adsorption in microporous manganese formate |
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| Authors: | Kim Hyunuk Samsonenko Denis G Yoon Minyoung Yoon Ji Woong Hwang Young Kyu Chang Jong-San Kim Kimoon |
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| Institution: | National Creative Research Initiative Center for Smart Supramolecules (CSS) and Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790-784, Korea. kkim@postech.ac.kr |
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| Abstract: | Microporous manganese formate shows temperature-triggered gate opening for nitrogen and argon adsorption, which is not due to a structural change of the framework but due to dynamic opening of the pore aperture and/or sufficient kinetic energy of the adsorbates to overcome a diffusion barrier above a critical temperature. |
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