Functionalised saturated-backbone carbene ligands: yttrium and uranyl alkoxy-carbene complexes and bicyclic carbene-alcohol adducts |
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Authors: | Arnold Polly L Casely Ian J Turner Zoë R Carmichael Christopher D |
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Institution: | School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, UK. |
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Abstract: | A new and modular route to bidentate ligands that combines an alkoxide with a saturated backbone N-heterocyclic carbene (NHC) is presented. The bi(heterocyclic) compounds are formally the addition product of a saturated NHC and the alcohol group of the N-functionalised arm. Using these compounds, the synthesis and structural characterisation of the first electropositive metal complexes of saturated N-heterocyclic carbenes has been achieved, and examples structurally characterised for the yttrium(III) and the uranyl UO(2)](2+) cations. |
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Keywords: | alkoxides bicyclic carbenes uranium uranyl yttrium |
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