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Synthesis of Allyl 2-Dialkylamino-4-pentenoates and Their Analogs via Stevens Rearrangement |
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| Authors: | Babakhanyan A V Shakhbazyan L G Grigoryan Dzh V Kocharyan S T |
| Institution: | (1) Abovyan Armenian State Pedagogical University, Zakaria Kanakertsi 167-A, Erevan, 375091, Armenia;(2) Institute of Organic Chemistry, National Academy of Sciences of Armenia, Erevan, Armenia |
| Abstract: | Stevens rearrangement of ammonium salts containing an allyloxycarbonylmethyl group in benzene in the presence of sodium phenoxide yields allyl 2-dialkylamino-4-pentenoates. The rearrangement in the presence of sodium methoxide is accompanied by transesterification to afford methyl 2-dialkylamino-4-pentenoates. |
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