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Magnetic and Luminescence Properties of Two Dinuclear Lanthanide Complexes with Butterfly‐like Arrangement |
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| Authors: | Qipeng Li Yanqiong Shen Yong Wang Ping Ye Lang Li Zejun Zhang |
| Abstract: | Two dinuclear lanthanide complexes with pentadentate ligand 3‐[bis(pyridine‐2‐ylmethyl)amino]propane‐1,2‐diol (H2L), formulated as [Ln2(HL)2(NO3)2(H2O)2] · 1.5NO3 · 0.5I [Ln = Tb ( ZTU‐1 ) and Eu ( ZTU‐2 ); ZTU = Zhaotong University] were synthesized and structurally characterized. ZTU‐1 and ZTU‐2 are isomorphous and feature a butterfly‐like arrangement. The fluorescence properties of ZTU‐1 and ZTU‐2 are investigated and slow magnetic relaxation behavior is observed in ZTU‐1 . |
| Keywords: | Dinuclear lanthanide complex Luminescence Lanthanides Slow magnetic relaxation |