| Synergy of Anodic Oxidation and Cathodic Reduction Leads to Electrochemical C—H Halogenation |
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| 作者姓名： | Zhilin Zhou Yong Yuan Yangmin Cao Jin Qiao Anjin Yao Jing Zhao Wanqing Zuo Wenjie Chen Aiwen Lei |
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| 作者单位： | National Research Center for Carbohydrate Synthesis;College of Chemistry and Molecular Sciences |
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| 基金项目： | the National Natural Science Foundation of China (No.21520102003);Introducing Talents of Discipline to Universities of China (111 Program). |
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| 摘 要： | We herein uncovered an electrochemical C—H halogenation protocol that synergistically combines anodic oxidation and cathodic reduction for C—X bond formation. The reaction was demonstrated under exogenous-oxidant-free conditions. Moreover, this is the first example of activating CBr4, CHBr3, and CCl3Br under electrochemical conditions.
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| 关 键 词： | anodic oxidation cathodic reduction ELECTROCHEMISTRY C-H HALOGENATION SYNTHETIC methods |
Synergy of Anodic Oxidation and Cathodic Reduction Leads to Electrochemical C—H Halogenation |
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| Zhilin Zhou,Yong Yuan,Yangmin Cao,Jin Qiao,Anjin Yao,Jing Zhao,Wanqing Zuo,Wenjie Chen,Aiwen Lei.Synergy of Anodic Oxidation and Cathodic Reduction Leads to Electrochemical C—H Halogenation[J].Chinese Journal of Chemistry,2019,37(6):611-615. |
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| Authors: | Zhilin Zhou Yong Yuan Yangmin Cao Jin Qiao Anjin Yao Jing Zhao Wanqing Zuo Wenjie Chen Aiwen Lei |
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| Abstract: | We herein uncovered an electrochemical C—H halogenation protocol that synergistically combines anodic oxidation and cathodic reduction for C—X bond formation. The reaction was demonstrated under exogenous‐oxidant‐free conditions. Moreover, this is the first example of activating CBr4, CHBr3, and CCl3Br under electrochemical conditions. |
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