Insensitive and Thermostable Energetic Materials Based on 3‐Ureido‐4‐tetrazole‐furazan: Synthesis,Characterization, and Properties |
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Authors: | Zhen Dong Dong An Rui Yang Zhiwen Ye |
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Abstract: | Energetic salts composed of ureido, furazan, and tetrazole were prepared by simple and efficient chemical routes to explore new insensitive and thermostable energetic materials. 3‐Ureido‐4‐tetrazole‐furazan ( 3 ) and its ammonium salt ( 5 ) and hydrazinium salt ( 6 ) were confirmed by single‐crystal X‐ray diffraction. The thermal stabilities of the synthesized salts were studied using differential scanning calorimetry, and the detonation performances of these salts were calculated using EXPLO 5 V6.01. All the salts exhibit good thermal stability (Td: 148–259 °C) and mechanical sensitivities (IS > 40 J, FS > 360 N), and their detonation velocities range from 7316 to 8655 m · s–1. Compounds 6 and 10 are potential candidates as novel insensitive and heat‐resistant explosives because of their high detonation temperatures of 247 and 256 °C, good detonation velocities of 8432 and 8523 m · s–1, and good detonation pressures of 25.6 and 26.8 GPa. |
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Keywords: | 3‐Ureido‐4‐tetrazole‐furazan Insensitive Thermostable Energetic material Single crystal |
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