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Ag‐Enhanced TiO2–x/C Composites with Metal‐Organic Frameworks as Precursors for Photodegradation of Methyl Blue
Authors:Dongmei Fan  Qing Xu
Abstract:A series of Ag‐enhanced TiO2–x/C composites (Ag/TiO2–x/C composites) with metal‐organic frameworks (MOFs) as precursors were prepared, and their photocatalytic activities were evaluated by the UV‐light driven photodegradation behaviors of methyl blue (MB). The as‐obtained samples were characterized by several techniques such as SEM, XRD, N2‐adsorption, XPS, UV/Vis spectrophotometry and UV/Vis diffuse‐reflectance spectra. The best photocatalytic performance was achieved in Ag/TiO2–x/C composite pyrolyzed at 1000 °C (ATC‐P10) due to rapid capture of electrons caused by silver doping, higher density of TiO2–x lattice oxygen vacancies for better trapping of electrons, and high surface area due to reduction and evaporation of metallic Zn. No obvious deactivation was observed after 10 cycles of UV‐light degradation of MB under the same experimental conditions. This report reveals a new approach to prepare stable and highly efficient UV‐light‐driven photocatalysts for organic pollutants in water.
Keywords:Ag/TiO2–  x/C composites  Silver  MOFs  Pyrolysis  Photodegradation
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