The cover picture shows a highly enantioselective organocatalytic protonation of monofluorinated silyl enol ethers to α‐secondary α‐fluoroketones using water as proton source. Notably, in the presence of D2O and MeOD, the facile access of chiral α‐deuterated α‐fluoroketones in excellent enantioselectivity is achieved. More details are discussed by Zhou et al. on page 799–806.