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The catalytic asymmetric Mannich-type reactions in aqueous media |
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| Authors: | Kobayashi Shū Hamada Tomoaki Manabe Kei |
| Affiliation: | Graduate School of Pharmaceutical Sciences, The University of Tokyo, CREST, Japan. |
| Abstract: | The catalytic, diastereo- and enantioselective Mannich-type reaction of a hydrazono ester with silyl enol ethers in aqueous media has been successfully achieved with ZnF(2), a chiral diamine ligand, and trifluoromethanesulfonic acid. |
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