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Speciation in strongly acidic metastable solutions of oxotungstate(vi) compounds
Authors:L. V. Pugolovkin  S. Yu. Vassiliev  M. I. Borzenko  V. K. Laurinavichyute  G. A. Tsirlina
Affiliation:1. Chemical Department, M. V. Lomonosov Moscow State University, Building 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation
Abstract:The ionic composition of long-lived metastable aqueous solutions of oxo compounds of tungsten(IV) with pH ≤ 1 was studied by spectrophotometry. The nature of some isopolytung-states formed in these solutions in the presence of various inorganic acids (HCl, HClO4, HNO3, H2SO4, and H2SeO4) was established.
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