Rhodium(III), palladium(II), and platinum(II) complexes with 2-(2-hydroxybenzoyl)-N-methylhydrazinecarbothioamide: Syntheses,structures, and spectral characteristics |
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| Authors: | S I Orysyk V V Bon O A Zholob V I Pekhnyo V V Orysyk Yu L Zborovskii M V Vovk |
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| Institution: | 1. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. akademika Palladina 32/34, Kiev, Ukraine
2. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, Ukraine
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| Abstract: | The syntheses and spectral (IR, UV-VIS, XPS, and 1H and 13C NMR) characteristics of the rhodium(III), palladium(II), and platinum(II) complexes with 2-(2-hydroxybenzoyl)-N-methylhydrazinecarbothioamide (HBMHCTA) are described. The coordination of HBMHCTA to the central metal ion and its intraligand rearrangement in the complex formation of rhodium(III) ions are studied. The structure of the mixed-ligand complex Pd(H2L)PPh3] is determined by X-ray diffraction analysis. |
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