| 烷基季铵盐插层剂的合成及应用 |
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| 引用本文： | 张青山,朱湛,王琦,王立杰,郭炳南. 烷基季铵盐插层剂的合成及应用[J]. 化学研究与应用, 2003, 15(6): 849-851 |
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| 作者姓名： | 张青山 朱湛 王琦 王立杰 郭炳南 |
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| 作者单位： | 北京理工大学化工与环境学院,北,京,100081 |
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| 基金项目： | 教育部留学回国人员基金项目资助(367-4) |
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| 摘 要： | Three novel intercalation agents were synthesized for the first time, which arose from oleic acid diethylenetriamine or triethylenetetramine 3 - chloro - 2 - hydroxypropy trimethylammonium choride (CHPTA) and chloroethanol. Organophilic vermicullites were synthesized from sodium type vermiculite by cation exchange with new intercalation agents. The results of X - ray diffraction study showed that the gallery distance of the organophilic vermiculite was enlarged from 1 nm to 5 nm or more. A new idea of making design for intercalation agent was provided.
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| 关 键 词： | 烷基季铵盐 插层剂 合成 应用 蛭石 锲型分子 双子型表面活性剂 |
| 文章编号： | 1004-1656(2003)06-0849-03 |
| 修稿时间： | 2003-01-06 |
Synthesis and application of new intercalation agents |
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| ZHANG Qing-shan,ZHU Zhan,WANG Ke,WANG Li-jie,GUO Bin-gnan. Synthesis and application of new intercalation agents[J]. Chemical Research and Application, 2003, 15(6): 849-851 |
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| Authors: | ZHANG Qing-shan ZHU Zhan WANG Ke WANG Li-jie GUO Bin-gnan |
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| Abstract: | Three novel intercalation agents were synthesized for the first time,which arose from oleic acid diethylenetriamine or triethylenetetramine 3-chloro-2-hydroxypropy trimethylammonium choride(CHPTA)and chloroethanol.Organophilic vermicullites were synthesized from sodium type vermiculite by cation exchange with new intercalation agents.The results of X-ray diffraction study showed that the gallery distance of the organophilic vermiculite was enlarged from 1 nm to 5 nm or more.A new idea of making design for intercalation agent was provided. |
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| Keywords: | intercalation agent vermiculite quaternary ammonium salt carving molecular geminisurfactant |
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