A metal-centered hydrophobic pocket recognizing pyridine over piperidine |
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| Authors: | Kim Ki-Hyun Song Rita Kim Kwan Mook |
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| Institution: | Life Science Division, Korea Institute of Science and Technology, Seoul 130-650, Korea. |
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| Abstract: | Two external spaces of an inorganic tennis ball are a novel type of metal-centered hydrophobic pocket where two hydrophobic trans-(+/-)-1,2-diaminocyclohexane groups stand perpendicularly to and around the metal coordination plane. The space recognizes pyridine over piperidine, and a novel supramolecule was obtained using such pyridine recognition properties. |
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