| 米托蒽醌在离子注入修饰电极上的伏安行为及其应用 |
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| 引用本文： | 胡劲波,李启隆.米托蒽醌在离子注入修饰电极上的伏安行为及其应用[J].高等学校化学学报,2001,22(3):380-384. |
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| 作者姓名： | 胡劲波 李启隆 |
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| 作者单位： | 北京师范大学化学系, 北京 100875 |
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| 基金项目： | 国家自然科学基金! (批准号 :2 9875 0 0 3 0 )，教育部博士学科点基金! (批准号 :980 0 2 70 9)资助 |
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| 摘 要： | 在0.1mol/LNH3-NH4Cl缓冲溶液(pH9.5)中,米托蒽醌在镍离子注入修饰电极上有一灵敏的伏安还原峰,峰电位为-0.85V(vs.SCE).峰电流与米托蒽醌的浓度成线性关系.检出限为1.8×10-8mol/L.研究了其伏安行为,并将该波用于尿样的测定.结果表明,还原过程为具有吸附性和催化性的准可逆过程.AES和XPS实验表明,Ni已注入到玻碳电极的表面,使电催化活性提高.
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| 关 键 词： | 离子注入修饰电极 伏安行为 米托蒽醌 |
| 文章编号： | 0251-0790(2001)03-0380-05 |
| 收稿时间： | 2000-02-02 |
Studies on the Voltammetric Behavior of Mitoxantrone and Its Application at the Ni/GC Modified Electrode |
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| HU Jing-bo,LI Qi-long.Studies on the Voltammetric Behavior of Mitoxantrone and Its Application at the Ni/GC Modified Electrode[J].Chemical Research In Chinese Universities,2001,22(3):380-384. |
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| Authors: | HU Jing-bo LI Qi-long |
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| Institution: | Department of Chemistry, Beijing Normal University, Beijing 100875, China |
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| Abstract: | In a 0.1 mol/L NH3-NH4Cl buffer solution(pH 9.50), a sensitive reduction peak of mitoxantrone at a Ni/GC modified electrode was obtained by linear-sweep voltammetry. The peak potential was -0.85 V(vs. SCE). The peak current was proportional to the concentration of mitoxantrone. The detection limit was 1.8×10-8 mol/L. Its voltammetric behavior was studied and the wave was applied to the determination of mitoxantrone in urine. The reduction process was quasi-reversible with adsorption and catalysis. AES and XPS experiments showed that Ni was surely implanted into the surface of the GCE, and the implanted Ni at the GC improved the electrocatalytic activity. |
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| Keywords: | Ion implanted modified electrode Voltammetric behavior Mitoxantrone |
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