Reaction of triphenylantimony and triphenylbismuth withtert-butyl peracetate |
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Authors: | A. V. Gushchin E. E. Dyomina V. A. Dodonov |
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Affiliation: | (1) N. I. Lobachevsky Nizhnii Novgorod State University, 23 prosp. Gagarina, 603600 Nizhnii Novgorod, Russian Federation |
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Abstract: | Triphenylantimony and triphenylbismuth diacetates, Ph3M(OAc)2 (M = Sb, Bi), were obtained in 50–94 % yields by the reaction of triphenylantimony and triphenylbismuth withtert-butyl peracetate in the presence of acetic acid or acetic anhydride (molar ratio 1 1 1) in toluene.tert-Butyl peracetate oxidizes Ph3M into alkoxides, Ph3M(OAc)OBut, which at the instant of formation are acylated with acetic acid or acetic anhydride to give the corresponding derivatives, Ph3M(OAc)2.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 964–967, May, 1995.This study was financially supported by the Russian Foundation for Basic Research (Grant 94-03-08846). |
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Keywords: | triphenylantimony, triphenylbismuth, oxidation tert-butyl peracetate triphenylantimony diacetate, triphenylbismuth diacetate tert-butylhydroperoxide |
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