A one-pot synthesis of a 243-allyl dendrimer under ambient conditions |
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Authors: | Ornelas Catia Aranzaes Jaime Ruiz Cloutet Eric Astruc Didier |
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Affiliation: | Nanosciences and Catalysis Group, LCOO, UMR CNRS No. 5802, ENSCPB, Université Bordeaux I, Talence, France. |
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Abstract: | [reaction: see text] Hydrosilylation of a nonaallyl dendritic core using HSi(Me)(2)Cl followed by reaction with a phenolate dendronic brick bearing three allyl groups, followed by repetition of this sequence of reactions twice, allows a one-pot synthesis of a 243-allyl dendrimer under ambient conditions. |
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