Arylene ethynylene macrocycles prepared by precipitation-driven alkyne metathesis |
| |
Authors: | Zhang Wei Moore Jeffrey S |
| |
Affiliation: | Roger Adams Laboratory, Departments of Chemistry and Materials Science & Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA. |
| |
Abstract: | A convenient, multigram-scale synthesis of arylene ethynylene macrocycles near room temperature is described. Driven by the precipitation of a diarylacetylene byproduct, alkyne metathesis produces the desired macrocycles in one step from monomers in high yields. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|