C2-symmetric bicyclo[3.3.1]nonadiene as a chiral ligand for rhodium-catalyzed asymmetric arylation of N-(4-nitrobenzenesulfonyl)arylimines |
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| Authors: | Otomaru Yusuke Tokunaga Norihito Shintani Ryo Hayashi Tamio |
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| Institution: | Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan. |
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| Abstract: | Reaction: see text] Asymmetric synthesis of diarylmethylamines with high enantioselectivity (95-99% ee) was realized by use of a new C2-symmetric diene ligand, (1R,5R)-2,6-diphenylbicyclo3.3.1]nona-2,6-diene (Ph-bnd), for the rhodium-catalyzed asymmetric arylation of N-(4-nitrobenzenesulfonyl)arylimines with arylboroxines. |
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