| TiO2-CdS-MCM-41复合纳米材料的合成和表征 |
| |
| 引用本文： | 陈锋,朱依萍,马宏燎,柏子龙,张金龙. TiO2-CdS-MCM-41复合纳米材料的合成和表征[J]. 物理化学学报, 2004, 20(11): 1292-1296. DOI: 10.3866/PKU.WHXB20041102 |
| |
| 作者姓名： | 陈锋 朱依萍 马宏燎 柏子龙 张金龙 |
| |
| 作者单位： | Institute of Fine Chemicals, East China University of Science and Technology; Institute of Petroleum Processing, East China University of Science and Technology, Shanghai 200237 |
| |
| 基金项目： | 国家自然科学基金(20073026)，上海市教委资助项目~~ |
| |
| 摘 要： | 利用γ-巯丙基三甲氧基硅烷及表面预吸附水解技术在MCM-41介孔分子筛孔道内部以化学键合的形式依次引入了CdS和TiO2纳米粒子.紫外-可见吸收光谱结果表明,借助于巯基的络合能力,MCM-41能有效地从反胶束中萃取CdS纳米粒子.利用小角XRD谱图成功地跟踪观察到了MCM-41介孔分子筛随纳米粒子的引入而产生的孔径变化.
|
| 关 键 词： | CdS TiO2 MCM-41 复合纳米材料 |
| 收稿时间： | 2004-03-25 |
| 修稿时间： | 2004-03-25 |
Preparation and Characterization of TiO2-CdS-MCM-41 Nano-composite |
| |
| Chen Feng Zhu Yi Ping Ma Hong Liao Bo Zi Long Zhang Jin Long. Preparation and Characterization of TiO2-CdS-MCM-41 Nano-composite[J]. Acta Physico-Chimica Sinica, 2004, 20(11): 1292-1296. DOI: 10.3866/PKU.WHXB20041102 |
| |
| Authors: | Chen Feng Zhu Yi Ping Ma Hong Liao Bo Zi Long Zhang Jin Long |
| |
| Affiliation: | Institute of Fine Chemicals, East China University of Science and Technology; Institute of Petroleum Processing, East China University of Science and Technology, Shanghai 200237 |
| |
| Abstract: | thiopropyl tri methyl silicane and surface pre adsorption hydrolysis technique were used to accommodate CdS and TiO2 nanoparticles into the tunnels of MCM 41 meso porous sieves.UV Vis spectra showed that MCM 41 extracted CdS nanoparticles effectively from the reverse micelles by the chelation of thiol groups.The changes of meso tunnel diameter of MCM 41 were also observed with the introducing of nanoparticles in the low angle XRD patterns. |
| |
| Keywords: | CdS TiO2 MCM 41 Nano composite |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
|
点击此处可从《物理化学学报》下载全文 |
