Synthesis of new bicyclic P-N ligands and their application in asymmetric Pd-catalyzed pi-allyl alkylation and Heck reaction |
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| Authors: | Gilbertson S R Genov D G Rheingold A L |
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| Institution: | Department of Chemistry, Washington University, One Brookings Drive, Campus Box 1034, St. Louis, Missouri 63170-4899, USA. srg@wuchem.wustl.edu |
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| Abstract: | structure: see text] The synthesis of phosphine oxazoline ligands based on P-chiral 1-phosphanorbornadienes is reported. The use of these ligands in palladium catalyzed asymmetric allylation and Heck reaction is described. |
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